© 2000 NATI Research JSC

       Introduction     Minerals    Discussion



   The common and special features of PGM occurrence in chromitites.
(Syum-Keu ultramafic complex, Polar Ural. Outocumpu ophiolites, Finland)

The data on chromitites of  Syum-Keu massif are author's data of NATI Research JSC,
obtained in performance of works by the order of All Russia Geological Institute, St. Petersburg.


Authors

Go Top        Introduction


The minerals of noble metals ( the elements of platinum group and gold) in chromitites of ultramafic complexes are well known in various tectonic structures of continents and oceans. Many researches are devoted to the investigation of chromitites and accessory PGM. But, despite of the low average contents of PGE in chromitites (n*10 - n*100ppb), the lists of noble metal minerals have dozens of mineral types.

It is obvious, that for sufficient completeness of studying of PGM mineralization with the low contents of PGE, it is necessary to investigate very much plenty of samples, because only in some of them it is possible to find out an individual PGM grains. However, observing individual PGM grains in individual samples it is extremely difficult to establish primary mineral paragenesises of PGM and to reveal subsequent thermal processes resulting in redistribution of PGE .

To obtain the most complete information about PGM the "ppm-mineralogy" technique was used. It allows to carry out the mineralogical research with high mineralogical sensibility in respect to PGM. Using ppm-mineralogy, it is possible to find and to study rather large number of PGM grains in each sample to get a notion of PGM history of ultramafic massif.

The data obtained as a result of study of Outocumpu ultramafic samples (chromitites) are placed in a special section of our site (see "PGMs in Outocumpu Ophiolite Complex "). The data on mineralogy of PGM in chromitites of Syum-Keu massif (Polar Ural), which have served as a material for realisation of the comparative analysis of PGM in both massifs, are given below.


Go Top        Minerals. Back Scattered Electron Microscope Images

syli46s.gif (4158 bytes)
1        (Full Image ~41K)
Euhedral sperrylite inclusion (SPR: PtAs2) in chromite (CRT). sy2a10s.gif (3227 bytes)
2        (Full Image ~28K)
Euhedral grain of laurite (LR): RuS2.
(The same is proper for Outocumpu chromitites).
syli11s.gif (1624 bytes)
3
         (Full Image ~ 9K)
Euhedral grain of sperrylite (SPR).
(The same is proper for Outocumpu chromitites).
sy2a25s.gif (2758 bytes)
4        (Full Image ~22K)
Euhedral grain of sperrylite (SPR).
(The same is proper for Outocumpu chromitites).
sy2b12s.gif (3090 bytes)
5
        (Full Image ~26K)
Euhedral grain of laurite-erlichmanite (LR-ER): (Ru,Os)S2.
(The same is proper for Outocumpu chromitites).
sy2b14s.gif (3078 bytes)
6
        (Full Image ~27K)
Euhedral grain of laurite  (LR) with inclusion of irarsite (IRS: IrAsS) and kashinite (KSH: (Ir,Rh)2S3. The shape of irarsite+kashinite inclusion is the same as inherented to gas-liquid inclusions.
sy2b47s.gif (3666 bytes)
7
        (Full Image ~35K)
Altered euhedral grain of laurite (LR). Dark spots - Ni-rich areas: heazlewoodite? (HSL Ni3S2). Laurite faces are deformed by irarsite (IRS). (Typical for Outocumpu chromitites). sy2a3s.gif (5335 bytes)
8
        (Full Image ~56K)
Altered euhedral grain of sperrylite (SPR). The same as shown on previous picture.
sy2a2s.gif (3637 bytes)
9        (Full Image ~34K)
Aggregate euhedral grain of laurite (LR) with native iridium-osmium alloy (Ir,Os). sy2b55s.gif (3922 bytes)
10       (Full Image ~40K)
Altered euhedral grain of laurite (LR) partly replaced by irarsite (IRS) and hollingwortite HGW: RhAsS.
(The same proper to Outocumpu chromitites).
sy2b15s.gif (2241 bytes)
11      (Full Image ~15K)
Altered grain of laurite (LR) spotly replaced by irarsite (IRS).
(The same is proper for Outocumpu chromitites).
sy2b37s.gif (4804 bytes)
12      (Full Image ~51K)
Altered euhedral grain of laurite (LR) partly replaced by Ni-sulphide: heazlewoodite(?) or millerite(?): MIL (NiS). Ni-sulphide replacement very usual for Outocumpu chromitites.
syk8s.gif (3266 bytes)
13      (Full Image ~32K)
Aggregate irarsite, heazlewoodite (Ni3S2) and millerite (NiS). syk1345s.gif (4549 bytes)
14      (Full Image ~46K)
Aggregate millerite (MIL), heazlewoodite (HSL), irarsite (IRS) and ullmannite ULM: NiSbS.
sy2b32s.gif (2347 bytes)
15      (Full Image ~17K)
Relict of euhedral laurite grain (LR) replaced by irarsite (IRS) and native ruthenium (Ru). syk3s.gif (2493 bytes)
16      (Full Image ~21K)
Native ruthenium-rhodium alloy.
syk9s.gif (5223 bytes)
17      (Full Image ~57K)
Native platinum with nickel. syk16s.gif (3676 bytes)
18      (Full Image ~32K)
Native platinum with nickel.
syk345s.gif (2333 bytes)
19      (Full Image ~19K)
Aggregate of (Ni,Fe) and (Fe,Ni) alloys. syli36s.gif (2384 bytes)
20      (Full Image ~18K)
Aggregate Pd-maucherite (MAU), majakite (MC: PdNiAs) and hessite HS: Ag2Te.
syli41s.gif (2950 bytes)
21      (Full Image ~25K)
Aggregate Pd-maucherite (MAU: Ni11As8) and sobolevskite SBL: Pd(Bi). syli22s.gif (2145 bytes)
22      (Full Image ~15K)
Euhedral grain of Pd-maucherite.
syli1s.gif (2620 bytes)
23      (Full Image ~20K)
Aggregate majakite (MC: PdNiAs) and atheneite ATN: (Pd,Hg)3As. syli2s.gif (2731 bytes)
24      (Full Image ~23K)
Grain of temagamite (TMG): Pd3HgTe3.
syli33s.gif (1897 bytes)
25      (Full Image ~12K)
Grain of electrum EL: AuAg. syli24s.gif (1987 bytes)
26      (Full Image ~13K)
Aggregate of Au-Ag-Cu-Fe(?) alloys.
syli29s.gif (2244 bytes)
27      (Full Image ~15K)
Grain of Cu-Au-Pd alloy. syg10s.gif (2199 bytes)
28      (Full Image ~17K)
Aggregate of native Pb, Sn, Cu.
sy2a27s.gif (2499 bytes)
29      (Full Image ~19K)
Aggregate of native Cu with euhedral laurite (LR).   Faces of laurite are not deformed by Cu. syli16s.gif (2583 bytes)
30      (Full Image ~21K)
Cu-Zn alloy with chromite relict (CRT).
syli54s.gif (5814 bytes)
31      (Full Image ~60K)
Cu-Zn alloy with magnetite inclusion (MGT). sy2b4s.gif (5847 bytes)
32      (Full Image ~60K)
Grain of native Zn.
sy2b902s.gif (4959 bytes)
33      (Full Image ~44K)
Native iron (Fe) and chromite relicts (CRT) in serpentine (SRP). sy2b68s.gif (1729 bytes)
34      (Full Image ~10K)
Native bismuth (Bi).
sy2b5s.gif (2274 bytes)
35      (Full Image ~18K)
Grain of cinnobar (HgS). syli49s.gif (4188 bytes)
36      (Full Image ~44K)
Aggregate of chromite (CRT), chalcopyrite (CP:CuFeS2) and chromium magnetite MGT: Fe(Fe,Cr)O4.
syli52s.gif (4575 bytes)
37      (Full Image ~48K)
Aggregate of pirrhotite (PO: FeS), chalcopyrite(CP) and serpentine (SRP). syli53s.gif (5688 bytes)
38      (Full Image ~63K)
Aggregate of cooper minerals: chalcopyrite (CP) and bornite (BN): Cu5FeS4.


Go Top      Discussion

The data given on photos 1 - 38 concern the Syum-Keu massif. These data in a combination to the data on mineralogy of noble metals of the Outocumpu ophiolite complex (see "PGMs in Outocumpu Ophiolite Complex"), allow to observe both common features and distinctions of PGE mineralization in these massifs.

Syum-Keu chromitites Outocumpu chromitites

     Crystallisation events
           Primary euhedral PGMs:
           Laurite (LR),
           Erlichmanite (ER),
           Sperrylite (SPR)

           Fig. 1-6                  gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)

                         Aftercrystallization
                            thermal events
                                        Replacement of primary
                                        LR, ER, SPR by
                                        Irarsite (IRS),
                                        Hollingwortite (HGW),
                                        Ni-sulphides

                                         Fig. 7-14                 pravi1.gif (1007 bytes)
                           tupik1.gif (993 bytes)arr_1.gif (1077 bytes)    

       Native events I                       gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)
           Ir-Os, Ru, Rh, Pt-Ni, Ni-Fe

           Fig. 9, 15-19                              
Pd-As events
                                                   The (PGE)(Te,Bi,Hg
) appearance
                                                               with arsenides.

                                                                 Fig. 20-24

                                                                pravi1.gif (1007 bytes)

                        tupik1.gif (993 bytes) arr_1.gif (1077 bytes)                  gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)
        Native events II
             Native Au, Ag, Cu, Zn,                       Sulphide
  
                         Fe, Pb, Sn, Bi
           mineralization
             Fig. 25-34                                    Fig. 35-38

 


     Crystallisation events
             Primary euhedral PGMs:
             Laurite (LR),
             Erlichmanite (ER),
             Sperrylite (SPR)

           Fig. 1-3                  gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)

                         Aftercrystallization
                            thermal events
                                        Replacement of primary
                                        LR, ER, SPR by
                                        Irarsite (IRS),
                                         Fig. 4-7                 pravi1.gif (1007 bytes)
                           tupik1.gif (993 bytes)arr_1.gif (1077 bytes)    

       Native events I                       gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)
           Not detected

                                                         
Pd-As events
                                        Pd mineralization not detected
                                         As-PGM - Anduoite: (Ru,Os)As2,
                                               Gersdorffite: (Ni,Ru,Os,Ir)AsS.
                                         Bi-Te phases- Hedleyite : Bi7Te3,
                                                                  NinBim, NiAs,
                                                Fig. 16,17

                                                                pravi1.gif (1007 bytes)

                       tupik1.gif (993 bytes) arr_1.gif (1077 bytes)                  gl_dor.gif (987 bytes)arr_2.gif (1056 bytes)
        Native events II
                 Native  Pb, Sn                            Sulphide
  
             Fig. 18
              
               mineralization
                                                              (present, but not shown)

 


The data given in the table allow to allocate the main stages of formation of PGE mineralization in chromitites of Syum-Keu and Outocumpue massifs and to carry out their comparison.

First two stages - Crystallisation and Aftercrystallization thermal events - almost precisely coincide in chromitites of both massifs: in both massifs idiomorphic crystals of laurite, erlichmanite and sperrylite are present. They are formed during crystallisation of chromitites. The presence of laurite grains in chromite with the high contents of Al2O3 (Fig.1) testifies it.
Idiomorphic grains of laurite, erlichmanite and sperrylite are replaced by irarsite hollingwortite and Ni-sulphide. These changes, probably, are connected with autometamorphic stage of chromitites transformation. (The exact identification of Ni-sulphides is complicated and there is no complete reliance of their diagnostics. It is possible, that these Ni-sulphides are not mineral phases themselves, but the fragments of laurite, enriched with Ni).

Post-crystallisation history of Syum-Keu and Outocumpu chromitites has much more distinctions, than similar features. It demonstrates that on the further history of massifs the main influence is rendered by specific features of a geological structure and development of regions, but not the features of mantle sources and not the process of intrusion of mantle matter into the upper horizons of the Earth crust. In other words, the post-crystallisation and post-autometamorphic history of massifs is a history of ultramafic complexes in the conditions of the crust.

The subsequent stages of PGE mineralization are connected with the processes of transformation of already generated chromitite horizons.They proceed with supply of such chemical elements as Pd, Bi, Te, Hg and partly As, which are absent or not typical for chromitites.

The specific feature of PGE mineralization of Syum-Keu chromitites is the well expressed stage of native mineralization: Ir, Os, Ru, Rh, Pt-Ni and Fe-Ni alloys (Native events I) are present. The last one is not founded out in investigated Outocumpu chromitites. Pd and Hg mineralization is not founded out also, and the stage " Native events II" is also reduced considerably.

It is possible to compare stages of PGE mineralization in chromitites to regional geological processes resulting in occurrence of this mineralization. For that case it is necessary to carry out the detailed work not only on mineralogy of PGM, but also on both petrography and mineralogy of rock-forming and sulphide minerals.

For Outocumpu chromitites it is possible to try to link the occurrence of (Ir, Os, Ru, Rh)-gersdorffites with one of the stages of younger regional metamorphism. But the stages of PGM formation in Syum-Keu chromitites are very much risky to interpret owing to insufficient geological study of ultramafic massif itself.

In summary it is important to specify one more obvious conclusion: for reconstruction of a history and genesis of PGE mineralization in anyone ultramafic complex it is completely not enough to base only on definitions of PGE concentration in the rocks and to plot the chondrite-normalised diagrams. Without the data on mineralogy - the history and genesis of PGE is "a black cat in a black room".

The given material shows (and it is well known from the literature), that the formation of PGE mineralization takes place in some occurring at different times stages and is accompanied by differentiation of PGE which may be studied by mineralogy only. Therefore, the definition of concentration of elements in a sample gives the researcher only figures. But if to obtain and operate only with these concentration figures, the information on genesis and information on history of formation of PGE mineralization (and ultramafic complex as well), is completely destroyed.

If the purpose of research is a knowledge about the nature of any phenomenon, it is necessary to choose such technique, which does not destroy the information on this phenomenon during obtaining the information.


       Introduction     Minerals    Discussion